qct calculations were performed to study the behavior of energized nh2oh formed by association collision of nh2 radical with oh radical. a potential energy surface that describes the behavior of the title reaction has been constructed by interpolation of ab initio data. h2o, hon, hno, nh3, o, h2no, cis or trans-honh, and h products and two vibrationally energized nh2oh and nh3o adducts were obs...

the hydroxyl radical (oh•) is a powerful oxidant produced as a consequence of cavitation in water. it can react nonspecifically in breaking down persistent organic pollutants in water into their mineral form. it can also recombine to form hydrogen peroxide which is very useful in water treatment. in this study, terephthalic acid (ta) and potassium iodide dosimetry were used to quantify and inve...

oxygen-derived free radical* (ofr) involvement in ischacmia-rcpcrfusion (ir) injury was investigated in a rat isolated kidney model, using 20 minutes iscliaemia followed by 15 or 60 minutes reperfusion. two antioxidants, the xanthine oxidase inhibitor allopurinol and the hydroxyl radical scavenger dimcthylthiourca (dmtu), were uscit to try and prevent ofr-relatcd damage. renal function was esti...

A vast majority of the studies addressing the free radicals including hydroxyl radical is a damage compound of biochemical molecules such as DNA, proteins and lipids. When free radicals specially hydroxyl radical are not adequately removed from the body, it may damage biological macromolecules, leading to a variety of disease occurs. Therefore, the body should be protected by an enzymatic or no...

background: one of the new methods for elimination or destruction of estrogen hormones is ultrasound irradiation. the aim of this study was to determine the main mechanism of steroid hormones removal by ultrasound. methods: in this study, estrogen (e1) and 17 beta-estradiol (e2) were irradiated with ultrasound at different frequencies, powers, and exposure times in two cases: with and without b...

a vast majority of the studies addressing the free radicals including hydroxyl radical is a damage compound of biochemical molecules such as dna, proteins and lipids. when free radicals specially hydroxyl radical are not adequately removed from the body, it may damage biological macromolecules, leading to a variety of disease occurs. therefore, the body should be protected by an enzymatic or no...

ethanolic extract of leaves of elaeocarpus ganitrus was analyzed for their total antioxidant capacity, reducing power, metal chelating, abts+ (2, 2-azinobis-(3-ethylbenzothiazoline-6-sulphonate) radical scavenging and hydroxyl radical scavenging activities. the extract at 500 ?g/ml showed maximum iron chelating activity (76.70%) followed by the scavenging of the abts+ radical (55.77%) at the sa...

Astaxanthin (Asx) is known to be a potent quencher of singlet oxygen and an efficient scavenger of superoxide anion. Therefore, Asx would be expected to be a useful antioxidant for the prevention of oxidative stress, a causative factor in severe diseases such as ischemic reperfusion injury. However, it is still unclear whether Asx has scavenging capability against the most potent reactive oxyge...

the hydrogen abstraction reaction by oh radical from ch2brch2br (r1) and ch₃chbr2 (r2) is investigated theoretically by semi-classical transition state theory. the stationary points for both reactions are located by using ωb97x-d and kmlyp density functional methods along with cc-pvtz basis. single-point energy calculations are performed at the qcisd(t) and ccsd(t) levels of theory with differe...